by Dave Donohue
Jun 14
Chemical of the Week – Part 2
Hazard Profile
Chemical Name and Pseudonyms
Ethyl Mercaptan, Ethanethiol, Ethyl Sulfhydrate, Mercaptoethane
UN Number
2363
Chemical Formula
CH3CH2SH
Hazards
Flammable liquid, skin/eye/respiratory irritant, toxic
PPE Considerations
SFPC with SCBA
Fire Fighting Considerations
Dry chemical, CO2 , ATC-AFFF
Decontamination
Flush skin/contact areas if exposed, soap and water
Detection and Monitoring
Colormetric, electrochemical sensor, 4/5-gas, IP=9.29 eV, GCMS
Chemical and Physical Properties
Physical State
Colorless liquid with skunk-like odor
Vapor Pressure
~442 mmHg
Boiling Point
~95oF
Vapor Density
~2.14
Specific Gravity
~.84
Miscibility
Soluble in water
Flash Point
-55oF
LEL/UEL
~2.6%/18%
Autoignition Temp
563oF
pH
-
Toxicity
IDLH
500 ppm
PEL/REL/STEL
.5 ppm / .5 ppm/ .5 ppm
LD50
682 mg/kg
LC50
11.23 mg/l
Radioactive (Yes/No)
No
Medical
Toxicological Considerations
Exposure by contact, inhalation, ingestion
Signs/Symptoms of Exposure
Respiratory symptoms, skin irritation, eye damage, liver/kidney damage, CNS symptoms
Medical Treatment
Fresh air and treat symptomatically, flush areas of contact with water
Other Information
Reacts with oxidizers, catalysts, esp. sodium hypochlorite
Chemical Structure
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Chemical of the Week Part 2 - Ethyl Mercaptan
by Dave Donohue
Jun 14
Chemical of the Week – Part 2
Hazard Profile
Chemical Name and Pseudonyms
Ethyl Mercaptan, Ethanethiol, Ethyl Sulfhydrate, Mercaptoethane
UN Number
2363
Chemical Formula
CH3CH2SH
Hazards
Flammable liquid, skin/eye/respiratory irritant, toxic
PPE Considerations
SFPC with SCBA
Fire Fighting Considerations
Dry chemical, CO2 , ATC-AFFF
Decontamination
Flush skin/contact areas if exposed, soap and water
Detection and Monitoring
Colormetric, electrochemical sensor, 4/5-gas, IP=9.29 eV, GCMS
Chemical and Physical Properties
Physical State
Colorless liquid with skunk-like odor
Vapor Pressure
~442 mmHg
Boiling Point
~95oF
Vapor Density
~2.14
Specific Gravity
~.84
Miscibility
Soluble in water
Flash Point
-55oF
LEL/UEL
~2.6%/18%
Autoignition Temp
563oF
pH
-
Toxicity
IDLH
500 ppm
PEL/REL/STEL
.5 ppm / .5 ppm/ .5 ppm
LD50
682 mg/kg
LC50
11.23 mg/l
Radioactive (Yes/No)
No
Medical
Toxicological Considerations
Exposure by contact, inhalation, ingestion
Signs/Symptoms of Exposure
Respiratory symptoms, skin irritation, eye damage, liver/kidney damage, CNS symptoms
Medical Treatment
Fresh air and treat symptomatically, flush areas of contact with water
Other Information
Reacts with oxidizers, catalysts, esp. sodium hypochlorite
Chemical Structure