by Dave Donohue
May 16
Chemical of the Week – Part 2
Hazard Profile
Chemical Name and Pseudonyms
Acetic Acid, Ethanoic Acid, Glacial Acetic Acid (pure compound), Methanocaboxylic Acid,
UN Number
2790 (10-80% acid), 2789 (>80% acid)
Chemical Formula
CH3COOH
Hazards
Corrosive, flammable
PPE Considerations
SFPC or CPC with SCBA
Fire Fighting Considerations
Dry chemical, dry powder, CO2, AR-AFFF. Keep tanks cool if exposed to fire/heat.
Decontamination
Flush skin/contact areas if exposed, soap and water
Detection and Monitoring
Colormetric, electrochemical sensor, 4/5-gas, IP=10.66 eV. Note use of electronic sensors only if equipment can be protected from corrosion.
Chemical and Physical Properties
Physical State
Colorless liquid or crystals with vinegar-like odor
Vapor Pressure
~11 mmHg
Boiling Point
~244oF
Vapor Density
~2.07
Specific Gravity
~1.05
Miscibility
Soluble in water
Flash Point
103oF
LEL/UEL
~4%/19%
Autoignition Temp
~800oF
pH
<2.5
Toxicity
IDLH
50 ppm
PEL/REL/STEL
10 ppm / 10 ppm/ 15 ppm
LD50
3310 mg/kg
LC50
>40 mg/l
Radioactive (Yes/No)
No
Medical
Toxicological Considerations
Significant irritant to skin, eyes, respiratory tract
Signs/Symptoms of Exposure
Respiratory symptoms, skin irritation/burns, eye damage
Medical Treatment
Fresh air and treat symptomatically, flush areas of contact with water
Other Information
Reacts with oxidizers and strong caustics, corrosive to metals and skin
Chemical Structure
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Chemical of the Week Part 2 - Acetic Acid
by Dave Donohue
May 16
Chemical of the Week – Part 2
Hazard Profile
Chemical Name and Pseudonyms
Acetic Acid, Ethanoic Acid, Glacial Acetic Acid (pure compound), Methanocaboxylic Acid,
UN Number
2790 (10-80% acid), 2789 (>80% acid)
Chemical Formula
CH3COOH
Hazards
Corrosive, flammable
PPE Considerations
SFPC or CPC with SCBA
Fire Fighting Considerations
Dry chemical, dry powder, CO2, AR-AFFF. Keep tanks cool if exposed to fire/heat.
Decontamination
Flush skin/contact areas if exposed, soap and water
Detection and Monitoring
Colormetric, electrochemical sensor, 4/5-gas, IP=10.66 eV. Note use of electronic sensors only if equipment can be protected from corrosion.
Chemical and Physical Properties
Physical State
Colorless liquid or crystals with vinegar-like odor
Vapor Pressure
~11 mmHg
Boiling Point
~244oF
Vapor Density
~2.07
Specific Gravity
~1.05
Miscibility
Soluble in water
Flash Point
103oF
LEL/UEL
~4%/19%
Autoignition Temp
~800oF
pH
<2.5
Toxicity
IDLH
50 ppm
PEL/REL/STEL
10 ppm / 10 ppm/ 15 ppm
LD50
3310 mg/kg
LC50
>40 mg/l
Radioactive (Yes/No)
No
Medical
Toxicological Considerations
Significant irritant to skin, eyes, respiratory tract
Signs/Symptoms of Exposure
Respiratory symptoms, skin irritation/burns, eye damage
Medical Treatment
Fresh air and treat symptomatically, flush areas of contact with water
Other Information
Reacts with oxidizers and strong caustics, corrosive to metals and skin
Chemical Structure